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961.
花岗岩源岩问题——关于花岗岩研究的思考之四 总被引:36,自引:18,他引:18
花岗岩源岩是花岗岩研究中最令人关注的问题之一,许多花岗岩的地球化学性质和分类实际上反映的是花岗岩的源岩问题.花岗岩幔源、壳源和壳幔混合源的说法被证明是不合适的,花岗岩不可能是幔源的,花岗岩都是壳源的,既然没有了幔源,也就无所谓壳幔混合源,因此,壳源本身也失去了意义.流行的花岗岩源岩组分混合计算的方法缺少理论依据,可变的因素太多,计算的结果可能没有多少实际意义.作者指出,对花岗岩来说第1位重要的是源区特征,它决定了花岗岩的基本面貌;其次是部分熔融程度、压力、温度和挥发分加入的情况;岩浆混合的意义可能是第3位的;而结晶分离作用可能是没有地位的.文中按照Nd-Sr同位素比值将花岗岩大致分为3个源区:即B、C和BC源区.B源主要由洋壳组成,C源主要由陆壳组成,BC源是二者的过渡.BC源区的组成很复杂,可能包括由交代地幔部分熔融形成的中基性岩浆岩,也可能是基性岩混染了陆壳物质的产物.B源与BC源可能与地幔亏损程度有关,B源来自强烈亏损的地幔,一部分BC源可能源于大陆下的富集地幔.文中还概略地讨论了中国各地花岗岩复杂的源区情况,指出中国花岗岩具区域性分布的特点说明花岗岩主要受源岩的制约. 相似文献
962.
皖东地区中酸性侵入岩为一套石英闪长岩-石英二长闪长岩-花岗闪长岩-二长花岗岩组合,主要属于高钾钙碱性岩系列,具有高Al2O3、Sr、Sr/Y、(La/Yb)N、富集LREE和LILE、亏损HREE和Y、Yb、Eu弱负异常—正异常、岩石高(87Sr/86Sr)i、低εNd(t)等特征。与中国东部多数埃达克质岩石相比,岩石具有较高的Mg#值和相容元素Cr、Ni含量。研究表明:(1)皖东地区中酸性侵入岩可能是拆沉的下地壳基性物质经部分熔融作用及岩浆在上升过程中与地幔橄榄岩相互反应的产物,石榴石作为残留相存在。(2)燕山早期皖东地区存在受特提斯构造域挤压构造控制的地壳加厚过程,早白垩世受太平洋构造域影响的郯庐断裂带大规模左行平移活动是触发下地壳拆沉的主要因素。皖东地区中酸性侵入岩是两大构造体制域发生转换的岩浆岩石记录。 相似文献
963.
辽西凌源地区义县组火山岩锆石U—Pb年代学和地球化学特征 总被引:3,自引:0,他引:3
对辽西凌源地区义县组的1件流纹岩样品进行锆石U—Pb年代学研究,获得的年龄为(124.4±1.4)Ma,与前人对辽西北票、义县、凌源等地区通过K—Ar、Ar—Ar、U—Pb等定年方法获得的义县组年龄基本一致,时代为早白垩世。7件典型火山岩样品的地球化学研究结果表明,该火山岩的SiO2=65.6%-73.4%,MgO=0.35%~1.23%,Mg^#=16~41,Al2O3=13.40%~16.79%,Na2O=3.54%-4.26%。Sr=(445~774)×10^-6,Yb=(0.51-0.97)×10^-6,V=(7~14)×10^-6,Sr/Y=49-66,LaN/YbN=33-48,高Sr和Sr/Y比值,低Y和Yb,轻重稀土元素分异明显,显示出埃达克岩的地球化学特征,但其Mg^#较低。它们可能是加厚的基性下地壳部分熔融的产物。 相似文献
964.
965.
966.
Ti-in-zircon thermometry: applications and limitations 总被引:16,自引:5,他引:11
Bin Fu F. Zeb Page Aaron J. Cavosie John Fournelle Noriko T. Kita Jade Star Lackey Simon A. Wilde John W. Valley 《Contributions to Mineralogy and Petrology》2008,156(2):197-215
The titanium concentrations of 484 zircons with U-Pb ages of ∼1 Ma to 4.4 Ga were measured by ion microprobe. Samples come
from 45 different igneous rocks (365 zircons), as well as zircon megacrysts (84) from kimberlite, Early Archean detrital zircons
(32), and zircon reference materials (3). Samples were chosen to represent a large range of igneous rock compositions. Most
of the zircons contain less than 20 ppm Ti. Apparent temperatures for zircon crystallization were calculated using the Ti-in-zircon
thermometer (Watson et al. 2006, Contrib Mineral Petrol 151:413–433) without making corrections for reduced oxide activities (e.g., TiO2 or SiO2), or variable pressure. Average apparent Ti-in-zircon temperatures range from 500° to 850°C, and are lower than either zircon
saturation temperatures (for granitic rocks) or predicted crystallization temperatures of evolved melts (∼15% melt residue
for mafic rocks). Temperatures average: 653 ± 124°C (2 standard deviations, 60 zircons) for felsic to intermediate igneous
rocks, 758 ± 111°C (261 zircons) for mafic rocks, and 758 ± 98°C (84 zircons) for mantle megacrysts from kimberlite. Individually,
the effects of reduced or , variable pressure, deviations from Henry’s Law, and subsolidus Ti exchange are insufficient to explain the seemingly low
temperatures for zircon crystallization in igneous rocks. MELTs calculations show that mafic magmas can evolve to hydrous
melts with significantly lower crystallization temperature for the last 10–15% melt residue than that of the main rock. While
some magmatic zircons surely form in such late hydrous melts, low apparent temperatures are found in zircons that are included
within phenocrysts or glass showing that those zircons are not from evolved residue melts. Intracrystalline variability in
Ti concentration, in excess of analytical precision, is observed for nearly all zircons that were analyzed more than once.
However, there is no systematic change in Ti content from core to rim, or correlation with zoning, age, U content, Th/U ratio,
or concordance in U-Pb age. Thus, it is likely that other variables, in addition to temperature and , are important in controlling the Ti content of zircon. The Ti contents of igneous zircons from different rock types worldwide
overlap significantly. However, on a more restricted regional scale, apparent Ti-in-zircon temperatures correlate with whole-rock
SiO2 and HfO2 for plutonic rocks of the Sierra Nevada batholith, averaging 750°C at 50 wt.% SiO2 and 600°C at 75 wt.%. Among felsic plutons in the Sierra, peraluminous granites average 610 ± 88°C, while metaluminous rocks
average 694 ± 94°C. Detrital zircons from the Jack Hills, Western Australia with ages from 4.4 to 4.0 Ga have apparent temperatures
of 717 ± 108°C, which are intermediate between values for felsic rocks and those for mafic rocks. Although some mafic zircons
have higher Ti content, values for Early Archean detrital zircons from a proposed granitic provenance are similar to zircons
from many mafic rocks, including anorthosites from the Adirondack Mts (709 ± 76°C). Furthermore, the Jack Hills zircon apparent
Ti-temperatures are significantly higher than measured values for peraluminous granites (610 ± 88°C). Thus the Ti concentration
in detrital zircons and apparent Ti-in-zircon temperatures are not sufficient to independently identify parent melt composition.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
967.
羌塘盆地侏罗系碎屑岩主要包括三角洲相、滨海相和河流相砂体,岩性以细砂岩和粉砂岩为主。储层经历了较强的压实作用和胶结作用,颗粒间线—凹凸接触,胶结物主要为钙质和硅质,储集空间以次生溶孔为主,包括颗粒溶孔、粒间溶孔等,溶孔以中孔和小孔为主,喉道为细喉和微喉,构造裂缝的发育对改善储层的渗透性有重要作用。物性统计表明:孔隙度大多小于5%,渗透率小于1mD,为低孔、低渗储层。结合低渗储层分类标准,将碎屑岩储集层分为3类进行了评价,认为上侏罗统雪山组储层最好,其次为中侏罗统雀莫错组,而夏里组相对较差;最有利储集层发育区主要位于北羌塘坳陷西部中央隆起带北缘和盆地东部雀莫错地区,较有利储层发育区位于北羌塘坳陷中部和东部地区,南羌塘坳陷储集层较差。压实作用和胶结作用较强,后期溶蚀作用相对较弱,是造成目前低孔低渗储层的主要因素。 相似文献
968.
湘南中生代花岗质岩石成岩成矿的时限 总被引:30,自引:1,他引:29
位于南岭中段的湘南地区,中生代花岗质岩石广泛分布;该区W、Sn、Pb、Zn、Mo、Bi等金属矿床密集产出,很多钨、锡矿床达到大型、超大型规模,且找矿潜力巨大,构成一个世界级的有色金属矿集区。最近大量的同位素年代学研究表明,南岭中段钨、锡、铅锌等金属的成矿是一个爆发性、区域性的地质事件,成矿时间高度集中,成矿时限主要在150~160 Ma之间,与该区主要花岗岩的成岩时间相当吻合;对单个钨、锡矿床而言,其矿区的成岩、成矿存在着一种准同期性,即成矿与矿区花岗岩的成岩基本上是同时的、或稍晚于花岗岩的成岩作用。因此,该区中生代的花岗岩与钨锡成矿作用具有明显的时、空联系。南岭中段花岗岩大规模的侵入和钨、锡等金属的爆发性成矿均形成于一种岩石圈伸展减薄、地壳拉张的构造环境,可能与华南中生代第二幕岩石圈伸展事件密切相关。 相似文献
969.
Two magma series and associated ore deposit types in the Permian Emeishan large igneous province, SW China 总被引:29,自引:0,他引:29
Mei-Fu Zhou Nicolas T. Arndt John Malpas Christina Yan Wang Allen K. Kennedy 《Lithos》2008,103(3-4):352-368
The Late Middle Permian ( 260 Ma) Emeishan large igneous province in SW China contains two magmatic series, one comprising high-Ti basalts and Fe-rich gabbroic and syenitic intrusions, the other low-Ti basalts and mafic–ultramafic intrusions. The Fe-rich gabbros are spatially and temporally associated with syenites. Each series is associated with a distinctive type of mineralization, the first with giant Fe–Ti–V oxide ore deposits such as Panzhihua and Baima, the second with Ni–Cu–(PGE) sulfide deposits such as Jinbaoshan, Limahe and Zhubu. New SHRIMP zircon U–Pb isotopic data yielded 263 ± 3 Ma for the Limahe intrusion, 261 ± 2 Ma for the Zhubu intrusion and 262 ± 2 Ma for a syenitic intrusion. These new age dates, together with previously reported SHRIMP zircon U–Pb ages, suggest that all these intrusions are contemporaneous with the Emeishan flood basalts and formed during a major igneous event at ca. 260 Ma.The oxide-bearing intrusions have higher Al2O3, FeO (as total iron) and total alkalis (Na2O + K2O) but lower MgO than the sulfide-bearing intrusions. All intrusions are variably enriched in LREE relative to HREE. The oxide-bearing intrusions display positive Nb- and Ti-anomalies and in certain cases negative Zr–Hf anomalies, whereas the sulfide-bearing intrusions have obvious negative Nb- and Ti-anomalies, a feature of crustal contamination. Individual intrusions have relatively small ranges of Nd(t) values. All the intrusions, however, have Nd(t) values ranging from − 3.9 to + 4.6, and initial 87Sr/86Sr ratios from 0.7039 to 0.7105. The syenites have very low MgO (< 2 wt.%) but highly variable Fe2O3 (2.5 to 13 wt.%) with initial 87Sr/86Sr ratios ranging from 0.7039 to 0.7089. Magmas from both series could have derived by melting of a heterogeneous mantle plume: the high-Ti series from a Fe-rich, more fertile source and the low-Ti series from a Fe-poor, more refractory source. In addition, the low-Ti series underwent significant crustal contamination. The two magma series evolved along different paths that led to distinct mineralization styles. 相似文献
970.
The Limahe Ni–Cu sulfide deposit is hosted by a small mafic–ultramafic intrusion (800 × 200 × 300 m) that is temporally associated
with the voluminous Permian flood basalts in SW China. The objective of this study is to better understand the origin of the
deposit in the context of regional magmatism which is important for the ongoing mineral exploration in the region. The Limahe
intrusion is a multiphase intrusion with an ultramafic unit at the base and a mafic unit at the top. The two rock units have
intrusive contacts and exhibit similar mantle-normalized trace element patterns and Sr–Nd isotopic compositions but significantly
different cumulus mineralogy and major element compositions. The similarities suggest that they are related to a common parental
liquid, whereas the differences point to magma differentiation by olivine crystallization at depth. Sulfide mineralization
is restricted to the ultramafic unit. The abundances of sulfides in the ultramafic unit generally increase towards the basal
contacts with sedimentary footwall. The δ
34S values of sulfide minerals from the Limahe deposit are elevated, ranging from +2.4 to +5.4‰. These values suggest the involvement
of external S with elevated δ
34S values. The mantle-normalized platinum-group element (PGE) patterns of bulk sulfide ores are similar to those of picrites
associated with flood basalts in the region. The abundances of PGE in the sulfide ores, however, are significantly lower than
that of sulfide liquid expected to segregate from undepleted picrite magma. Cr-spinel and olivine are present in the Limahe
ultramafic rocks as well as in the picrites. Mantle-normalized trace element patterns of the Limahe intrusion generally resemble
those of the picrites. However, negative Nb–Ta anomalies, common features of contamination with the lower or middle crust,
are present in the intrusion but absent in the picrites. Sr–Nd isotopes suggest that the Limahe intrusion experienced higher
degrees of contamination with the upper crust than did the picrites. The results of this study permit us to suggest that the
parental magma of the Limahe intrusion was derived from picritic magma by olivine fractionation and contamination in a staging
chamber at mid-crustal levels. Depletion of PGE in the sulfide ores in the Limahe intrusion is likely due to previous sulfide
segregation of the parental magmas in the staging chamber. Sulfide mineralization in the Limahe intrusion is related to second-stage
sulfide segregation after the fractionated magmas acquired external S from pyrite-bearing country rocks during magma ascent
to the Limahe chamber. The abrupt change in mineralogical and chemical compositions between the ultramafic unit and the overlying
unit suggests that at least two separate pulses of magma were involved in the development of the Limahe intrusion. We propose
that the Limahe intrusion was once a wider part of a dynamic conduit that fed magma to the overlying subvolcanic dykes/sills
or lavas. The ultramafic unit formed by the first, relatively more primitive magma, and the mafic unit formed by the second,
relatively more fractionated magma. Immiscible sulfide droplets that segregated from the first magma settled down with olivine
crystals to form the sulfide-bearing, olivine-rich rocks in the base of the intrusion. The overlying residual liquids were
then pushed out of the chamber by the second magma. Critical factors for the formation of an economic Ni–Cu sulfide deposit
in such a small intrusion include the dynamic petrologic processes involved and the availability of external sulfur. The Limahe
deposit reminds us that small, multiphase, mafic–ultramafic intrusions in the region should not be overlooked for the potential
of economic Ni–Cu sulfide deposits. 相似文献